|
|
5,6,7,8-tetrahydromethanopterin + L-glutamate + ATP <=> H+ + tetrahydrosarcinapterin + ADP + phosphate
|
6.3.2.33
tetrahydrosarcinapterin synthase
|
–
|
BK
|
| |
BRENDA:
BR49212
KEGG:
R09594
MetaCyc:
RXN-11103
|
|
|
|
a_[methyl-Co(III)_corrinoid_Fe-S_protein] + tetrahydrosarcinapterin <=> [Co(I)_corrinoid_Fe-S_protein] + 5-methyltetrahydrosarcinapterin + H+
|
2.1.1.245
5-methyltetrahydrosarcinapterin---corrinoid/iron-sulfur protein Co-methyltransferase
|
–
|
M
|
| |
BRENDA:
BR50039
MetaCyc:
RXN-12908
|
|
|
|
methyl-CoM + tetrahydrosarcinapterin <=> 5-methyltetrahydrosarcinapterin + coenzyme_M
|
2.1.1
2.1.1.86
tetrahydromethanopterin S-methyltransferase
|
–
–
|
M
|
| |
BRENDA:
BS432630
MetaCyc:
MTRMBARK-RXN
|
|
|
|
acetyl-CoA + tetrahydrosarcinapterin <=> CoA + 5-methyltetrahydrosarcinapterin + CO
|
not assigned
|
–
|
K
|
| |
KEGG:
R10219
|
|
|
|
methylcorrinoid_protein + tetrahydrosarcinapterin <=> corrinoid + 5-methyltetrahydrosarcinapterin
|
2.1.1.245
5-methyltetrahydrosarcinapterin---corrinoid/iron-sulfur protein Co-methyltransferase
|
–
|
|
| |
KEGG:
R10385
|
|
|
|
tetrahydrosarcinapterin + acetyl-CoA + H2O + oxidized_ferredoxin <=> 5-methyltetrahydrosarcinapterin + CO2 + CoA + reduced_ferredoxin_[iron-sulfur]_cluster + H+
|
2.3.3
|
–
|
|
| |
MetaCyc:
CDHMSARC-RXN
|
|
|
|
5-formyl-tetrahydrosarcinapterin + methanofuran <=> formylmethanofuran + tetrahydrosarcinapterin + H+
|
2.3.1.101
formylmethanofuran---tetrahydromethanopterin N-formyltransferase
|
–
|
M
|
| |
MetaCyc:
FTRMBARK-RXN
|
|
|
|
methanol + tetrahydrosarcinapterin <=> 5-methyltetrahydrosarcinapterin + H2O
|
not assigned
|
–
|
|
| |
MetaCyc:
METHTRANSBARK-RXN
|
|
|
|
H2 + CO2 + CH3-H4SPt + CoA <=> acetyl-CoA + tetrahydrosarcinapterin + H2O
|
3.1.2.1
acetyl-CoA hydrolase
|
–
|
|
| |
BRENDA:
BS73431
|
|
|
|
tetrahydrosarcinapterin + acetyl-CoA + H2O <=> CH3-H4SPt + CO2 + CoA
|
1.2.7.4
anaerobic carbon monoxide dehydrogenase
|
–
|
|
| |
BRENDA:
BS258315
|
|
|
|
GTP + 5,6,7,8-tetrahydromethanopterin + L-glutamate <=> GDP + phosphate + tetrahydrosarcinapterin
|
6.3.2.33
tetrahydrosarcinapterin synthase
|
–
|
|
| |
BRENDA:
BR49213
|
|
|
|
CH3-H4SPt + cob(I)amide-protein + H+ <=> tetrahydrosarcinapterin + CH3-cob(III)amide-protein
|
2.1.1.245
5-methyltetrahydrosarcinapterin---corrinoid/iron-sulfur protein Co-methyltransferase
|
–
|
|
| |
BRENDA:
BS418541
|
|
|
|
CH3-H4SPt + CO + CoA <=> CH3-CO-S-CoA + tetrahydrosarcinapterin
|
2.3.1.169
CO-methylating acetyl-CoA synthase
|
–
|
|
| |
BRENDA:
BS359568
|
|
|
|
CH3-CO-S-CoA + tetrahydrosarcinapterin + H2O <=> CH3-H4SPt + CO2 + H+ + e-
|
2.3.1.169
CO-methylating acetyl-CoA synthase
|
–
|
|
| |
BRENDA:
BS359572
|
|
